Superior Refinery Explosion 2018: Causes, Failures, and Lessons Learned
Incident Overview
- Date: April 26, 2018
- Location: Superior Refinery, Superior, Wisconsin
- Event: Large explosion during a maintenance shutdown punctured an asphalt tank, igniting a massive fire.
- Impact: 36 workers injured, ~US$550 million in damage, 39,000 lb of flammable hydrocarbon vapor released, 2,500+ residents evacuated, shelter‑in‑place order in Duluth, MN.
FCC Unit Shutdown Procedure
- The fluid catalytic cracker (FCC) cracks heavy hydrocarbons into lighter products.
- Normal operation relies on a balanced pressure between the reactor (hydrocarbon side) and the regenerator (air side) using slide valves.
- For shutdown, operators stopped hydrocarbon flow, closed both slide valves, and halted catalyst circulation.
- One slide valve was eroded; catalysts fell through, leaving an open path for air to flow backward into the reactor.
Chain of Events Leading to the Explosion
- Air Back‑flow: Without a reactor steam barrier, air from the regenerator entered the reactor and downstream equipment, creating a flammable air‑hydrocarbon mixture.
- Ignition: Around 10:00 a.m., the mixture found an ignition source, causing a large explosion.
- Debris Impact: Debris traveled ~200 ft, puncturing an above‑ground asphalt storage tank.
- Asphalt Spill & Fire: Hot asphalt spilled, flowed through the plant, and ignited around noon, producing a massive plume of black smoke.
- Fire Suppression: Emergency responders used dry chemical extinguishers and water; the fire was contained by 7:00 p.m., much faster than the typical multi‑day burn.
Six Safety Issues Identified by the CSB
- Transient‑Operation Safeguards – No reactor steam barrier; pressure differential forced air into the reactor; lack of nitrogen/gas purge.
- Process Knowledge – In‑house FCC expertise was isolated; no external technical review for 25+ years; shutdown procedures contradicted licensor guidance.
- Process Safety Management (PSM) Systems – Incomplete safety information, inadequate hazard analyses for transient states, insufficient operator training.
- Industry Knowledge & Guidance – Lessons from a similar 2017 Exxon‑Mobil explosion were not applied; no unified FCC safety publication existed.
- Brittle Fracture of Vessels – Older steel grades shattered under explosion pressure, sending high‑velocity fragments; newer, tougher steel could have reduced projectile hazards.
- Emergency Preparedness – Near‑miss with hydrofluoric acid (HF) storage; asphalt spill not treated as a flammable liquid quickly enough, allowing fire to spread.
Recommendations Made by the CSB
- Cenovus Energy (new owners): Implement FCC‑specific safeguards for transient operations and embed them in written procedures.
- Cenovus: Create a technology‑specific knowledge‑sharing network, including an FCC peer network.
- OSHA: Develop guidance for Process Hazard Analyses that address transient‑operation hazards.
- American Petroleum Institute (API): Publish a publicly available technical guide on safe FCC operation.
- EPA: Prioritize inspections of FCC units paired with HF alkylation units to verify explosion‑prevention safeguards.
Aftermath
- Refinery remained offline for over four years.
- 36 workers sought medical attention.
- Community disruption for thousands of residents.
- The incident is classified as a serious near‑miss involving HF, underscoring the potential for far worse consequences.
Key Lessons for the Industry
- Never rely solely on equipment designed for normal operation during shutdowns. Dedicated safeguards (steam barriers, inert gas purges) are essential.
- Maintain up‑to‑date process knowledge through regular external reviews and peer networking.
- Ensure PSM systems cover transient states with robust hazard analyses and operator training.
- Adopt modern materials to avoid brittle fracture in extreme events.
- Treat all spills of flammable liquids, even high‑viscosity materials like asphalt, as immediate fire hazards to enable rapid response.
The Superior refinery disaster shows that inadequate safeguards, outdated procedures, and insufficient process knowledge during shutdowns can turn a routine maintenance event into a catastrophic explosion and fire, emphasizing the need for robust transient‑operation safety systems across the refining industry.
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